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Varhaisimmat valurautaesineet löysivät arkeologit nykyisen Luhen piirikunnan alueelta Jiangsun osavaltiossa Aasiassa. Uusin rigvedan nimi ayas (metalli) viittaa kupariin, jos kyseessä on rauta, jota joskus kutsutaan nimellä śyāma ayas, kirjaimellisesti "musta kupari". Varhaisin mainitaan rigvedan Atharvavedan artikkelissa. Meteoriittimetalli on suhteellisen sileää ja sitkeää, ja se taotaan helpommin, mutta se voi heikentyä kuumennettaessa nikkelirakenteissa.